PRODUCTION OF ETHYLENE EPISULFIDE FROM LASER IRRADIATION OF SULFUR SURFACES IN THE PRESENCE OF ETHYLENE

被引：10

作者：

BETTERIDGE, DR ^{[1
]}

YARDLEY, JT ^{[1
]}

机构：

[1] ALLIED CHEM CORP,CORP RES CTR,MORRISTOWN,NJ 07960

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 62卷 / 03期

关键词：

D O I：

10.1016/0009-2614(79)80765-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

KrF laser irradiation of a sulfur surface in the presence of ethylene vapor has yielded ethylene episulfide: a non-thermal laser-induced heterogeneous reaction. The yield depends upon incident intensity to the 3.5 power; it increases linearly with ethylene pressure below 20 torr and falls off inversely with total pressure above 200 torr. Possible mechanisms are discussed. © 1979.

引用

页码：570 / 572

页数：3

共 17 条

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[2] BETTERIDGE D, UNPUBLISHED
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[8] KANTSKY H, 1933, CHEM BER, V66, P1588
[9] Karlov N. V., 1977, Soviet Physics - Uspekhi, V20, P721, DOI 10.1070/PU1977v020n09ABEH005460
[10] HETEROGENEOUS PHOTOSENSITIZATION
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JAMES, FC
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