ALLENE EPOXIDATION - HIGHLY FUNCTIONALIZED TETRAHYDROFURANS AND TETRAHYDROPYRANS FROM THE OXIDATIVE CYCLIZATION OF ALLENIC ALCOHOLS

被引：27

作者：

CRANDALL, JK

BATAL, DJ

LIN, F

REIX, T

NADOL, GS

NG, RA

机构：

[1] Department of Chemistry, Indiana University, Bloomington

来源：

TETRAHEDRON | 1992年 / 48卷 / 08期

关键词：

D O I：

10.1016/S0040-4020(01)92232-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The dimethyldioxirane oxidation of various allenic alcohols yields highly functionalized tetrahydrofuran and tetrahydropyran derivatives via intramolecular nucleophilic addition of the hydroxy group to an intermediate allene diepoxide.

引用

页码：1427 / 1448

页数：22

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