DISPIROKETALS IN SYNTHESIS .13. FUNCTIONALIZED DISPIROKETALS AS NEW CHIRAL AUXILIARIES - HIGHLY STEREOSELECTIVE DIELS-ALDER REACTIONS USING A BIFUNCTIONAL, C-2-SYMMETRICAL CHIRAL AUXILIARY

被引：14

作者：

BEZUIDENHOUDT, BCB ^{[1
]}

CASTLE, GH ^{[1
]}

GEDEN, JV ^{[1
]}

LEY, SV ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,DEPT CHEM,CAMBRIDGE CB1 2EW,ENGLAND

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 40期

关键词：

D O I：

10.1016/0040-4039(94)85339-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Highly selective, asymmetric, Lewis acid catalysed Diels-Alder reactions are reported with a bifunctional, C-2-symmetrical diacrylate derivative obtained from a chiral auxiliary based on dihydroxylated dispiroketals.

引用

页码：7451 / 7454

页数：4

共 3 条

[1] ASYMMETRIC DIELS-ALDER CYCLO-ADDITION REACTIONS WITH CHIRAL ALPHA, BETA-UNSATURATED N-ACYLOXAZOLIDINONES [J].

EVANS, DA ;

CHAPMAN, KT ;

BISAHA, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (04) :1238-1256

[2] ALPHA,BETA-UNSATURATED OXAZOLINES, A POWERFUL TOOL IN ASYMMETRIC DIELS-ALDER CYCLOADDITIONS [J].

KOUKLOVSKY, C ;

POUILHES, A ;

LANGLOIS, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (18) :6672-6679

[3] SYNTHESES AND CHIROPTICAL PROPERTIES OF (+)-2-BRENDANONE AND ITS ANALOGS [J].

NAKAZAKI, M ;

NAEMURA, K ;

KONDO, Y .

JOURNAL OF ORGANIC CHEMISTRY, 1978, 44 (01) :16-20

← 1 →