GENERATION OF SOLUTIONS OF HIGHLY PERSISTENT RADICAL CATIONS BY 4-TOLYLTHALLIUM(III) BIS(TRIFLUOROACETATE) IN 1,1,1,3,3,3-HEXAFLUOROPROPAN-2-OL

被引：35

作者：

EBERSON, L ^{[1
]}

HARTSHORN, MP ^{[1
]}

PERSSON, O ^{[1
]}

机构：

[1] UNIV CANTERBURY,DEPT CHEM,CHRISTCHURCH 1,NEW ZEALAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 11期

关键词：

D O I：

10.1039/c39950001131

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

4-Tolylthallium(III) bis(trifluoroacetate) acts as a one-electron oxidant toward aromatic substrates in trifluoroacetic acid or 1,1,1,3,3,3-hexafluoropropan-2-ol, the latter solvent giving radical cation solutions of uniquely high persistency at room temperature.

引用

页码：1131 / 1132

页数：2

共 17 条

[1] ELECTRON-SPIN RESONANCE-SPECTRA OF ALKYL ARYL ETHER RADICAL CATIONS
DIXON, WT
MURPHY, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1976, (15): : 1823 - 1828
[2] PHOTOCHEMICAL NITRATION BY TETRANITROMETHANE .11. ISOLATION AND X-RAY STRUCTURAL-ANALYSIS OF AN ANOMALOUS CIS-1-NITRO 2-TRINITROMETHYL ADDUCT FROM 1,4,5,8-TETRAMETHYLNAPHTHALENE
EBERSON, L
CALVERT, JL
HARTSHORN, MP
ROBINSON, WT
[J]. ACTA CHEMICA SCANDINAVICA, 1993, 47 (10): : 1025 - 1034
[3] THE RADICAL-CATION FROM HEXAMETHYL(DEWAR BENZENE) - DERIVED FROM A SUBSTITUTION PRODUCT OF HEXAMETHYLBENZENE
EBERSON, L
PERSSON, O
SVENSSON, JO
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (02) : 219 - 220
[4] FORMATION OF 1,2,4,5,6,8-HEXAMETHYLANTHRACENE AND ITS RADICAL-CATION FROM 2,2',3,4',5,5',6-HEPTAMETHYLDIPHENYLMETHANE IN TRIFLUOROACETIC-ACID
EBERSON, L
RADNER, F
LINDGREN, M
[J]. ACTA CHEMICA SCANDINAVICA, 1993, 47 (08): : 835 - 840
[5] THERMAL AND PHOTOCHEMICAL-REACTIONS OF AROMATIC-COMPOUNDS IN TRIFLUOROACETIC-ACID, INVOLVING CARBOCATIONS AND RADICAL CATIONS
EBERSON, L
RADNER, F
[J]. ACTA CHEMICA SCANDINAVICA, 1992, 46 (07): : 630 - 643
[6] EBERSON L, 1995, IN PRESS ACTA CHEM S, V49
[7] EBERSON L, 1995, IN PRESS J CHEM S P2
[8] THALLIUM(III) IN ONE-ELECTRON OXIDATION OF ARENES BY ELECTRON-SPIN RESONANCE
ELSON, IH
KOCHI, JK
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (15) : 5060 - 5062
[9] FLEISCHHAUER J, 1982, Z NATURFORSCH A, V87, P680
[10] FRITZ HP, 1981, ELECTROCHIM ACTA, V26, P417, DOI 10.1016/0013-4686(81)85031-1

← 1 2 →