AURANTIAMIDES - A NEW CLASS OF MODIFIED DIPEPTIDES FROM PIPER-AURANTIACUM

被引:54
作者
BANERJI, A
RAY, R
机构
关键词
D O I
10.1016/0031-9422(81)80116-1
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Two new amides, aurantiamide and aurantiamide acetate, were isolated from P. aurantiacum. Their structures were determined as N-(N''-benzoyl-S-benzoyl-S-phenylalaninyl)-S-phenylalaninol and its acetate, respectively, from chemical and spectroscopic studies. The structures and stereochemistry were confirmed by synthesis. The corresponding diastereoisomers were also synthesized and their spectroscopic properties compared with those of the natural compounds.
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页码:2217 / 2220
页数:4
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