OBSERVATION OF A CONTINUUM IN ENHANCED RAMAN-SCATTERING FROM A METAL-SOLUTION INTERFACE

被引：93

作者：

BIRKE, RL ^{[1
]}

LOMBARDI, JR ^{[1
]}

GERSTEN, JI ^{[1
]}

机构：

[1] CUNY CITY COLL,DEPT PHYS,NEW YORK,NY 10031

来源：

PHYSICAL REVIEW LETTERS | 1979年 / 43卷 / 01期

关键词：

D O I：

10.1103/PhysRevLett.43.71

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

A background continuum in the Raman spectrum of adsorbed molecules at a silverelectrolyte interface is observed experimentally. This background continuum is potential dependent on the Stokes and anti-Strokes of the spectrum and fits a Fermi distribution function on the anti-Stokes side of the spectrum. The continuum is interpreted in terms of radiative recombination of adsorbed molecular ions produced by photoionization. © 1979 The American Physical Society.

引用

页码：71 / 75

页数：5

共 18 条

[1] INTENSE RAMAN-SPECTRA AT A ROUGHENED SILVER ELECTRODE
ALBRECHT, MG
CREIGHTON, JA
[J]. ELECTROCHIMICA ACTA, 1978, 23 (10) : 1103 - 1105
[2] NATURE OF AN ELECTROCHEMICALLY ROUGHENED SILVER SURFACE AND ITS ROLE IN PROMOTING ANOMALOUS RAMAN-SCATTERING INTENSITY
ALBRECHT, MG
EVANS, JF
CREIGHTON, JA
[J]. SURFACE SCIENCE, 1978, 75 (04) : L777 - L780
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ALBRECHT, MG
CREIGHTON, JA
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[4] GIANT RAMAN-SCATTERING BY ADSORBED MOLECULES ON METAL-SURFACES
BURSTEIN, E
CHEN, YJ
CHEN, CY
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[J]. SOLID STATE COMMUNICATIONS, 1979, 29 (08) : 567 - 570
[5] RAMAN-SPECTRUM OF ADSORBED IODINE ON A PLATINUM-ELECTRODE SURFACE
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REID, ES
HENDRA, PJ
FLEISCHMANN, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (06) : 2002 - 2003
[6] DEPENDENCE OF INTENSITY OF RAMAN BANDS OF PYRIDINE AT A SILVER ELECTRODE ON WAVELENGTH OF EXCITATION
CREIGHTON, JA
ALBRECHT, MG
HESTER, RE
MATTHEW, JAD
[J]. CHEMICAL PHYSICS LETTERS, 1978, 55 (01) : 55 - 58
[7] RAMAN-SPECTRA OF PYRIDINE ADSORBED AT A SILVER ELECTRODE
FLEISCHMANN, M
HENDRA, PJ
MCQUILLAN, AJ
[J]. CHEMICAL PHYSICS LETTERS, 1974, 26 (02) : 163 - 166
[8] ANOMALOUSLY INTENSE RAMAN-SCATTERING AT THE SOLID-ELECTROLYTE INTERFACE
FURTAK, TE
[J]. SOLID STATE COMMUNICATIONS, 1978, 28 (11) : 903 - 906
[9] GERSTEN J, UNPUBLISHED
[10] HERITAGE J, COMMUNICATION

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