PHOTOELECTRON SPECTROSCOPIC STUDY OF [RH(CO)2CL]2

被引：6

作者：

DICKSON, RS

CARNOVALE, F

PEEL, JB

机构：

[1] LA TROBE UNIV,DEPT PHYS CHEM,BUNDOORA 3083,VICTORIA,AUSTRALIA

[2] LA TROBE UNIV,ELECTR SPECT RES CTR,BUNDOORA 3083,VICTORIA,AUSTRALIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 179卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)87801-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The He(I) and He(II) vapor phase photoelectron spectra of the [Rh(CO)2Cl]2 dimer have been measured and interpreted with the aid of the results of a non-empirical pseudopotential calculation. The relative He(I)/He(II) band intensity ratios indicate that the spectrum is essentially divided into Rh 4d, Cl 3p and CO σ,π ionization regions. Ionization potential shifts between the free and complexed moieties suggest that there is only a small nett transfer of electron density from Rh to Cl and CO. © 1979.

引用

页码：115 / 122

页数：8

共 21 条

[1] PHOTOELECTRON SPECTROSCOPIC STUDY OF SOME PENTACARBONYLCHROMIUM CARBENE COMPLEXES
BLOCK, TF
FENSKE, RF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (13) : 4321 - 4330
[2] DINUCLEAR-BRIDGED D8 METAL-COMPLEXES .4. CRYSTAL AND MOLECULAR-STRUCTURE OF [RHCL(CO)(P(CH3)2C6H5)]2 AND ISOMERIZATION IN SOLUTION OF [RHCL(CO)(PR3)]2 COMPLEXES
BONNET, JJ
JEANNIN, Y
KALCK, P
MAISONNAT, A
POILBLANC, R
[J]. INORGANIC CHEMISTRY, 1975, 14 (04) : 743 - 747
[3] Bullitt J.G., 1971, INORG CHIM ACTA, V5, P637
[4] PHOTOELECTRON-SPECTRA OF THE N-CHLORO AND N-BROMO DERIVATIVES OF DIMETHYLAMINE
CARNOVALE, F
GAN, TH
PEEL, JB
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1979, 32 (04) : 719 - 725
[5] INTERPRETATION OF PHOTOELECTRON-SPECTRUM OF CO CHEMISORBED ON NI
CEDERBAUM, LS
DOMCKE, W
NIESSEN, WV
BRENIG, W
[J]. ZEITSCHRIFT FUR PHYSIK B-CONDENSED MATTER, 1975, 21 (04): : 381 - 388
[6] CRYSTAL STRUCTURE OF DI-MU-CHLORO-BIS(TRIPHENYL PHOSPHITE)- (CYCLO-OCTA-1,5-DIENE)DIRHODIUM(I)
COETZER, J
GAFNER, G
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1970, B 26 : 985 - &
[7] CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CHLORIDE DIMER ETHYL ACETATE
CURTIS, MD
BUTLER, WM
GREENE, J
[J]. INORGANIC CHEMISTRY, 1978, 17 (10) : 2928 - 2931
[8] STRUCTURE OF AND METAL-METAL BONDING IN RH(CO)2CL
DAHL, LF
MARTELL, C
WAMPLER, DL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (07) : 1761 - &
[9] COMPARISON OF HE-I AND HE-II PHOTOELECTRON-SPECTRA OF PHOSPHORYL CHLORIDE
GAN, TH
PEEL, JB
WILLETT, GD
[J]. CHEMICAL PHYSICS LETTERS, 1977, 48 (03) : 483 - 486
[10] INFRARED SPECTRA AND DIPOLE MOMENTS OF RH2(CO)4CL2 AND RH2(CO)4BR2
GARLAND, CW
WILT, JR
[J]. JOURNAL OF CHEMICAL PHYSICS, 1962, 36 (04) : 1094 - &

← 1 2 3 →