PREPARATIVE-SCALE ORGANOMETALLIC CHEMISTRY IN SUPERCRITICAL FLUIDS - ISOLATION OF [CR(CO)5(C2H4)] AS A STABLE SOLID AT ROOM-TEMPERATURE

被引：32

作者：

BANISTER, JA ^{[1
]}

HOWDLE, SM ^{[1
]}

POLIAKOFF, M ^{[1
]}

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 24期

关键词：

D O I：

10.1039/c39930001814

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A miniature flow reactor has been developed for photochemical reactions in supercritical fluids; [Cr(CO)5(C2H4)] is isolated, for the first time, by the UV photolysis of [Cr(CO)6] in supercritical C2H4 at room temp. with a yield of ca. 40 mg per hour at ca. 80% purity as estimated by IR spectroscopy.

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页码：1814 / 1815

页数：2

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