ENZYMATIC BROMO-ETHER CYCLIZATION OF LAUREDIOLS WITH BROMOPEROXIDASE

被引：41

作者：

FUKUZAWA, A

AYE, M

TAKASUGI, Y

NAKAMURA, M

TAMURA, M

MURAI, A

机构：

[1] HOKKAIDO UNIV, FAC SCI, DEPT CHEM, SAPPORO, HOKKAIDO 060, JAPAN

[2] HOKKAIDO UNIV, INST ELECTR SCI, SAPPORO, HOKKAIDO 060, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 12期

关键词：

D O I：

10.1246/cl.1994.2307

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Natural (3E,6R,7R)- and (3Z,6S,7S)-laurediols were subjected to enzymatic reaction with the partially purified bromoperoxidase from the red alga, Laurencia nipponica, in the presence of H2O2 and NaBr to afford laurencin and prelaureatin, respectively. The further reaction of these products with bromoperoxidase gave rise to the bicyclic bromo-ethers.

引用

页码：2307 / 2310

页数：4

共 8 条

[1]

Erickson K. L., 1979, MARINE NATURAL PRODU, V5, P131, DOI DOI 10.1016/B978-0-12-624005-4.50011-2

[2] ENZYMATIC SINGLE-STEP FORMATION OF LAUREATIN AND ITS KEY INTERMEDIATE, PRELAUREATIN, FROM (3Z,6S,7S)-LAUREDIOL [J].