CONSTITUENTS OF CIGARETTE SMOKE .X. EVIDENCE FOR 1,5-HYDROGEN TRANSFER IN FORMATION OF NON-CONJUGATED ISOPRENOID POLYOLEFINS DURING PYROLYSIS

被引：5

作者：

DARE, DL

ENTWISTL.ID

JOHNSTON.RA

机构：

[1] Robert Robinson Laboratories, University of Liverpool

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1968年 / 08期

关键词：

D O I：

10.1039/j39680000977

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A major group of compounds present in cigarette smoke condensate are the polyolefins (I) which are not present in fresh or cured tobacco leaf. Studies on deuterium-labelled model olefins have provided evidence for specific 1,2- and 1,5-migrations of hydrogen at temperatures in the range 300-400° and suggest the role of a similar mechanism in the formation of the polyolefins (I).

引用

页码：977 / &

共 27 条

[1] BLACK DK, 1966, CHEM IND-LONDON, P197
[2] DARE DL, 1966, CHEM IND-LONDON, P629
[3] CONSTITUENTS OF CIGARETTE SMOKE .9. PYROLYSIS OF POLYENES AND FORMATION OF AROMATIC HYDROCARBONS
EDMUNDS, FS
JOHNSTONE, RA
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1965, (APR): : 2892 - +
[4] EVERETT JL, 1950, J CHEM SOC, P3133
[5] GROSSMAN JD, 1962, CHEM IND-LONDON, P1950
[6] GRUBB HM, 1963, MASS SPECTROMETRY OR, P491
[7] HAAGENSMIT AJ, 1954, CALIF HEALTH, V11, P129
[8] SYNTHESE VON SQUALEN AUS NATURLICHEM UND SYNTHETISCHEM NEROLIDOL
ISLER, O
RUEGG, R
CHOPARDDITJEAN, L
WAGNER, H
BERNHARD, K
[J]. HELVETICA CHIMICA ACTA, 1956, 39 (03) : 897 - 904
[9] SYNTHESE UND ISOLIERUNG VON VITAMIN-K2 UND ISOPRENOLOGEN VERBINDUNGEN
ISLER, O
RUEGG, R
CHOPARDDITJEAN, LH
WINTERSTEIN, A
WISS, O
[J]. HELVETICA CHIMICA ACTA, 1958, 41 (03) : 786 - 807
[10] PHYTADIENES AND NORPHYTENE, AND THEIR RELATION TO SOME COMPONENTS OF CIGARETTE SMOKE
JOHNSTONE, RAW
QUAN, PM
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1963, (DEC): : 5706 - &

← 1 2 3 →