TRIPLET-TRIPLET ENERGY-TRANSFER FROM BENZOPHENONE TO TRIS(2,2'-BIPYRIDINE)RUTHENIUM(II) CHLORIDE IN ACETIC-ACID - RELEVANCE OF TRIVIAL ABSORPTION EFFECTS

被引：6

作者：

FAVARO, G

MASETTI, F

RAMADORI, R

机构：

[1] Dipartimento di Chimica, Universitá di Perugia

来源：

JOURNAL OF PHOTOCHEMISTRY | 1979年 / 10卷 / 05期

关键词：

D O I：

10.1016/0047-2670(79)87001-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Energy transfer from benzophenone to Ru(bipy)2+3 has been studied in acetic acid by phosphorescence quenching of the donor and phosphorescence sensitization of the acceptor. A general method is described for the correction of trivial effects on the Stern-Volmer plots when both absorption and emission spectra of the donor overlap the absorption spectrum of the acceptor. The combination of intensity and lifetime data indicates that the quenching is not simply diffusional. © 1979.

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页码：349 / 357

页数：9

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