AZAPHOSPHATRANES AND PRO-AZAPHOSPHATRANES

被引：9

作者：

SCHMIDT, H

XI, SK

LENSINK, C

VERKADE, JG

HALL, G

机构：

[1] Department of Chemistry, Iowa State University, Ames, Iowa, 50010, Gilman Hall

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1990年 / 49卷 / 1-4期

关键词：

D O I：

10.1080/10426509008038932

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of P(MeNCH2CH2)3N, a new powerfully basic pro-azaphosphatrane, are discussed. Some of these reactions, such as oxidation with chalcogens and adduct formation with BH3and CS2, lead to pro-azaphosphatranes in which the phosphorus has become formally tetracoordinate. Other reactions, such as protonation or oxidation followed by BF3 adduct formation leads to HP(MeNCH2CH2)3N+ and F3BOP(MeNCH2CH2)3N, respectively, which possess phosphatrane structures featuring five-coordinate phosphorus. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：163 / 168

页数：6

共 5 条

[1]

LENSINK C, 1989, J AM CHEM SOC, V70, P1063

[2] BICYCLIC AND TRICYCLIC PHOSPHATRANES - CONDITIONS FOR TRANSANNULAR P]-N BONDING IN A NEW CLASS OF PHOSPHORUS CAGE COMPOUNDS [J].