APPROXIMATE SEPARATION OF THE HYPERRADIUS IN THE MANY-PARTICLE SCHRODINGER-EQUATION

被引:11
作者
AVERY, J [1 ]
GOODSON, DZ [1 ]
HERSCHBACH, DR [1 ]
机构
[1] HARVARD UNIV,DEPT CHEM,CAMBRIDGE,MA 02138
关键词
D O I
10.1002/qua.560390503
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
For large values of d = 3N, the radial distribution function of an N-particle system is sharply peaked near the hyperradius r(m) = (d - 2)/2k0, where k0 = (2\E\)1/2. This fact allows an approximate separation of the hyperradius, leading to many-dimensional hydrogenlike radial solutions. Kindred applications to dimensional scaling are also discussed, where d = DN, with D the spatial dimension. For the large D regime, illustrative analytic formulas are obtained giving the energy and effective nuclear charge for the lowest few S states of the helium atom.
引用
收藏
页码:657 / 666
页数:10
相关论文
共 27 条
[1]  
[Anonymous], 1955, MOL VIBRATIONS
[2]  
AVERY J, 1989, HYPERSPHERICAL HARMO
[3]  
BERRY RS, 1982, 15TH JER S QUANT CHE
[4]  
BERRY RS, 1983, NEW HORIZONS QUANTUM
[5]   2-ELECTRON ATOMS NEAR THE ONE-DIMENSIONAL LIMIT [J].
DOREN, DJ ;
HERSCHBACH, DR .
JOURNAL OF CHEMICAL PHYSICS, 1987, 87 (01) :433-442
[6]   ELECTRONIC-STRUCTURE FROM SEMICLASSICAL DIMENSIONAL EXPANSIONS - SYMMETRY-BREAKING AND BOUND-STATES OF THE HYDRIDE ION [J].
DOREN, DJ ;
HERSCHBACH, DR .
JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (07) :1816-1821
[7]   CORRELATION OF 2 PARTICLES ON A SPHERE [J].
EZRA, GS ;
BERRY, RS .
PHYSICAL REVIEW A, 1982, 25 (03) :1513-1527
[8]  
FANO U, 1982, ATOMIC COLLISIONS SP
[9]   ELECTRON CORRELATION CALIBRATED AT THE LARGE DIMENSION LIMIT [J].
GOODSON, DZ ;
HERSCHBACH, DR .
JOURNAL OF CHEMICAL PHYSICS, 1987, 86 (09) :4997-5008
[10]   RECURSIVE CALCULATION OF DIMENSIONAL EXPANSIONS FOR 2-ELECTRON ATOMS [J].
GOODSON, DZ ;
HERSCHBACH, DR .
PHYSICAL REVIEW LETTERS, 1987, 58 (16) :1628-1631