THE 1ST EXAMPLES OF 2,2'-6',2''-TERPYRIDINE AS A FLUXIONAL BIDENTATE LIGAND

被引：60

作者：

ABEL, EW ^{[1
]}

LONG, NJ ^{[1
]}

ORRELL, KG ^{[1
]}

OSBORNE, AG ^{[1
]}

PAIN, HM ^{[1
]}

SIK, V ^{[1
]}

机构：

[1] UNIV EXETER,DEPT CHEM,EXETER EX4 4QD,DEVON,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 04期

关键词：

D O I：

10.1039/c39920000303

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2,2':6',2"-Terpyridine (terpy) forms octahedral complexes fac-[ReBr(CO)3(terpy)], cis-[W(CO)4(terpy)] and fac-[PtClMe3(terpy)] in which the ligand oscillates between equivalent bidentate forms by a mechanism involving a 'tick-tock' twist of the metal moiety through an angle equal to the N-M-N angle of the octahedral centre and involving a seven-coordinate metal intermediate.

引用

页码：303 / 304

页数：2

共 9 条

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