PERFLUOROALKYLATIONS AND PERFLUOROOXAALKYLATIONS .2. COPPER MEDIATED CROSS-COUPLING OF SECONDARY PERFLUOROOXAALKYL IODIDES AND ARYL HALIDES

被引:18
作者
CHEN, GJ [1 ]
CHEN, LS [1 ]
EAPEN, KC [1 ]
机构
[1] UNIV DAYTON,RES INST,DAYTON,OH 45469
关键词
D O I
10.1016/S0022-1139(00)80474-1
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The first successful application of the copper-mediated cross-coupling reaction using secondary perfluorooxaalkyl iodides and iodoaromatic substrates is described. The yields of the cross-coupled products are optimized by careful choice and control of the experimental conditions. The by-products formed are identified and their probable mode of formation is discussed.
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页码:59 / 65
页数:7
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