UNSATURATED-COMPOUNDS OF SILICON AND ITS GROUP HOMOLOGS .37. UNSATURATED TIN-COMPOUNDS - GENERATION AND REACTIVITY OF ME2SN=C(SIME3)2 AND ME2SN=N(SITBU2ME)

被引：28

作者：

WIBERG, N

VASISHT, SK

机构：

[1] Institut Für Anorganische Chemie, Universität München, W-8000

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 01期

关键词：

D O I：

10.1002/anie.199100931

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stannaethene 1, which is hardly stablized electronically, was obtained by salt elimination and its existence was shown by trapping reactions with 2,3-dimethylbutadiene and azido(di-tert-butyl)methylsilane. Stannanimine 2, formed from the azidosilane, can be ''stored'' as the cycloadduct 3.

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页码：93 / 95

页数：3

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