PROTON SCAVENGING IN PHOTOACID GEMINATE RECOMBINATION PROCESSES

被引：36

作者：

GOLDBERG, SY

PINES, E

HUPPERT, D

机构：

[1] Raymond and Beverly Sackler Faculty of Exact Sciences, School of Chemistry, Tel Aviv University, Tel Aviv

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 192卷 / 01期

关键词：

D O I：

10.1016/0009-2614(92)85431-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Proton geminate recombination is observed in reversible excited-state intermolecular proton transfer reactions. Introducing a proton scavenger into the solution reduces the proton geminate recombination yield. At low scavenger concentrations the experimental data are in excellent agreement with a newly developed diffusive model.

引用

页码：77 / 81

页数：5

共 17 条

[1] GEMINATE RECOMBINATION IN PROTON-TRANSFER REACTIONS .2. COMPARISON OF DIFFUSIONAL AND KINETIC SCHEMES [J].