SOLVENT EFFECTS ON THE 2-DIMENSIONAL CONDENSATION OF 2-THIOURACIL

被引：13

作者：

WANDLOWSKI, T ^{[1
]}

CHAIYASITH, P ^{[1
]}

BAUMGARTL, H ^{[1
]}

机构：

[1] FREE UNIV BERLIN,INST PHYS & THEORET CHEM,W-1000 BERLIN 33,GERMANY

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1993年 / 346卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(93)85018-C

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The adsorption of 2-thiouracil at the mercury electrode from nonaqueous acetonitrile and benzonitrile was studied at 283.0 K. In both systems the formation of condensed layers at positive charge densities was observed. The presence of bulk water significantly influences the structure of ordered films formed by 2-thiouracil at the mercury-acetonitrile interface.

引用

页码：271 / 279

页数：9

共 36 条

[1] COMPUTER-SIMULATIONS OF THE DIELECTRIC-PROPERTIES OF WATER - STUDIES OF THE SIMPLE POINT-CHARGE AND TRANSFERABLE INTERMOLECULAR POTENTIAL MODELS [J].

ALPER, HE ;

LEVY, RM .

JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (02) :1242-1251

[2]

Amokrane S, 1992, MODERN ASPECTS ELECT, P1

[3]

Bard A. J., 2001, ELECTROCHEMICAL METH, V2nd, P50

[4]

BATTISTI AD, 1903, J ELECTROANAL CHEM, V48, P213

[5]

BLOMGREEN E, 1972, J PHYS CHEM-US, V65, P920

[6] THE ELECTRICAL DOUBLE-LAYER AT THE MERCURY SOLUTION INTERFACE IN ORGANIC-SOLVENTS [J].

BORKOWSKA, Z .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 244 (1-2) :1-13

[7] A THEORETICAL-STUDY ON THE WATER-STRUCTURE FOR NUCLEIC-ACIDS BASES AND BASE-PAIRS IN SOLUTION AT T=300-K [J].

CLEMENTI, E ;

CORONGIU, G .

JOURNAL OF CHEMICAL PHYSICS, 1980, 72 (07) :3979-3992

[8] DIELECTRIC CONSTANT + INTERMOLECULAR ASSOCIATION OF SOME LIQUID NITRILES [J].

DANNHAUSER, W ;

FLUECKINGER, AF .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (07) :1814-+

[9] STRUCTURE OF MERCURY-ETHYLENE CARBONATE INTERFACE .2. ADSORPTION OF IODIDE ION FROM SOLUTIONS OF CONSTANT IONIC-STRENGTH [J].

FAWCETT, WR ;

MACKEY, MD .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1973, 69 (07) :1153-1161

[10]

Franks F., 1972, WATER COMPREHENSIVE, V1-7

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