THE REACTION OF 9-BROMOANTHRACENE WITH BENZENETHIOLATE ANION IN TETRAGLYME - EVIDENCE AGAINST A COMPETING ELECTRON-TRANSFER MECHANISM

被引：4

作者：

BAUMGARNER, CD ^{[1
]}

MALEN, AH ^{[1
]}

PASTOR, SD ^{[1
]}

NABIRAHNI, MA ^{[1
]}

机构：

[1] PACE UNIV,DEPT CHEM,PLEASANTVILLE,NY 10570

来源：

HELVETICA CHIMICA ACTA | 1992年 / 75卷 / 02期

关键词：

D O I：

10.1002/hlca.19920750207

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of 9-bromoanthracene (1) with benzenethiol(ate) in tetraglyme proceeds by a S(N)Ar mechanism. The concurrent formation of anthracene is not due to a competing single-electron-transfer pathway involving either benzenethiol or benzenethiolate anion.

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收藏

页码：480 / 486

页数：7

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