THE DOUBLE-LAYER IMPEDANCE AT A ROUGH-SURFACE - NUMERICAL RESULTS

被引：19

作者：

LEIBIG, M

HALSEY, TC

机构：

[1] UNIV CHICAGO,JAMES FRANCK INST,5640 S ELLIS AVE,CHICAGO,IL 60637

[2] UNIV CHICAGO,DEPT PHYS,CHICAGO,IL 60637

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1993年 / 358卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0022-0728(93)80432-H

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

In this study we consider the relationship between the double-layer impedance at a rough surface and the statistical properties of random walks that are reflected from such a surface. We describe a numerical method that uses this relationship to calculate the impedance. Along with the details of our particular implementation, we present results for classes of rough surfaces for which there are theoretical predictions for the impedance behavior: self-similar surfaces, hierarchical pore structures and a random surface model.

引用

页码：77 / 109

页数：33

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