SPECTROELECTROCHEMICAL CHARACTERIZATION OF A PYRAZINE-BRIDGED MIXED-VALENT (4D5/4D6) ORGANOMETALLIC ANALOG OF THE CREUTZ-TAUBE ION

被引：25

作者：

BRUNS, W

KAIM, W

WALDHOR, E

KREJCIK, M

机构：

[1] UNIV STUTTGART, INST ANORGAN CHEM, PFAFFENWALDRING 55, D-70550 STUTTGART, GERMANY

[2] CZECHOSLOVAK ACAD SCI, J HEYROVSKY INST PHYS CHEM & ELECTROCHEM, CZ-18223 PRAGUE, CZECHOSLOVAKIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 24期

关键词：

D O I：

10.1039/c39930001868

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dinuclear complex ion transmer-[(PPri3)2(CO)3Mo(mu-PZ)MO(CO)3(PPri3)2]+ (pz = pyrazine), the closest yet reported organometallic analogue of the Creutz-Taube ion [(NH3)5Ru(mu-pz)Ru(NH3)5]5+, has been characterized as a fully delocalized Mo0.5/Mo0.5 system by electrochemistry, EPR, electronic and vibrational absorption spectroscopy.

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页码：1868 / 1869

页数：2

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