SYNTHESIS OF POLY(4-VINYL-1,4-BUTYROLACTONE-CO-CYANOETHYLENE)

被引：9

作者：

SHIMIDZU, T

YOSHIKAWA, M

HASEGAWA, M

FUJIMOTO, H

机构：

[1] Department of Hydrocarbon Chemistry, Kyoto University, Kyoto

来源：

POLYMER JOURNAL | 1979年 / 11卷 / 08期

关键词：

Copoly-merization; Frontier electron density; Poly(4-vinyl-L4-butyrolactone-co-cyanocthylene); Radical reactivity index; Radical reactivity ratio;

D O I：

10.1295/polymj.11.607

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Copolymerization of 4-vinyl-1, 4-butyrolactone (1) and cyanoethylene (2) initiated by 2, 2′-azobisisobutyronitrile were carried out. The following reactivity ratios were found for the bulk copolymerization at 50°C for 1, r1=0.004, and for 2, r2=4.4. Radical reactivity indices and frontier electron densities for 1, 2, and 3-vinyl-1, 4-butyrolactone were calculated. © 1979, The Society of Polymer Science, Japan. All rights reserved.

引用

页码：607 / 611

页数：5

共 13 条

[1]

FRUNZE TM, 1970, VYSOKOMOL SOEDIN A, V12, P460

[2]

FUJIMOTO H, 1972, ADV QUANTUM CHEM, V6

[3]

FUKUI K, 1970, THEORY ORIENTATION S

[4]

Fukui K., 1964, MOL ORBITALS CHEM PH

[5]

GABRIELYAN GA, 1963, KHIM VOLOKNA, V5, P2

[6] ANALYSIS OF LINEAR METHODS FOR DETERMINING COPOLYMERIZATION REACTIVITY RATIOS .1. NEW IMPROVED LINEAR GRAPHIC METHOD [J].

KELEN, T ;

TUDOS, F .

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1975, A 9 (01) :1-27

[7]

MATSUOKA K, 1965, KOGYO KAGAKU ZASSHI, V68, P1135

[8]

ONYON PF, 1965, J POLYM SCI, V22, P13

[9]

Pople J, 1970, APPROXIMATE MOL ORBI

[10] THE MALONIC ESTER SYNTHESIS WITH STYRENE OXIDE AND WITH BUTADIENE OXIDE [J].

RUSSELL, RR ;

VANDERWERF, CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1947, 69 (01) :11-13

← 1 2 →