DEHYDROGENATIVE COPOLYMERIZATION ON NEW POLYSILANE COPOLYMERS POLY(METHYL-CO-PHENYLSILANE) H[(MESIH)X(PHSIH)Y]NH AND POLY(METHYL-CO-DIMETHYLSILANE) H[(MESIH)X(ME2SI)Y]NH

被引：18

作者：

HENGGE, E

WEINBERGER, M

机构：

[1] Institut für Anorganische Chemie, Technische Universität Graz

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 441卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)80171-S

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dehydrogenative copolymerization of PhSiH3 with MeH2SiSiH2Me and of Me2HSiSiH2Me with MeH2SiSiH2Me by means of CP2MMe2 (Cp = C5H5, M = Ti, Zr) afforded the new polysilane-copolymers poly(methyl-co-phenylsilane) H[(MeSiH)x(PhSiH)y]nH and poly(methyl-co-dimethylsilane) H[(MeSi)x(Me2Si)y]nH. The progress of copolymerization is investigated and analyzed by gas liquid chromatography (GLC) and GLC-mass spectrometry (GLC-MS). A variety of new organosilicon compounds, formed at the beginning of the copolymerization, were identified by GLC-MS analysis.

引用

页码：397 / 410

页数：14

共 6 条

[1]

CLAUSS K, 1962, LIEBIGS ANN CHEM, V654, P8

[2] DEHYDROGENATIVE POLYMERIZATION OF DISILANES CATALYZED BY TITANOCENE AND ZIRCONOCENE COMPLEXES - A NOVEL ROUTE TO OLIGOSILANES AND POLYSILANES [J].