REVERSIBLE COVALENT ATTACHMENT OF C-60 TO A FURAN-FUNCTIONALIZED RESIN

被引：25

作者：

NIE, B ^{[1
]}

HASAN, K ^{[1
]}

GREAVES, MD ^{[1
]}

ROTELLO, VM ^{[1
]}

机构：

[1] UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01003

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 21期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0040-4039(95)00578-Z

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of Merrifield's peptide resin with the sodium anion of furfuryl alcohol provides a furan-functionalized polymer resin. This polymer reacts rapidly with C-60 to provide a fullerene-substituted polymer, presumably via Diels-Alder reaction, with the furan as diene and the fullerene as dienophile. This resin is greater than two-fold more efficient in C-60 uptake, and provides a 66% increase in C-60 release upon heating, compared with the previously reported cyclopentadiene-functionalized resin.

引用

页码：3617 / 3618

页数：2

共 11 条

[1] ORGANIC MOLECULAR SOFT FERROMAGNETISM IN A FULLERENE-C60 [J].

ALLEMAND, PM ;

KHEMANI, KC ;

KOCH, A ;

WUDL, F ;

HOLCZER, K ;

DONOVAN, S ;

GRUNER, G ;

THOMPSON, JD .

SCIENCE, 1991, 253 (5017) :301-303

[2]

GECKELER KE, 1993, J AM CHEM SOC, V115, P9836

[3] KINETIC STABILITY OF THE C-60-CYCLOPENTADIENE DIELS-ALDER ADDUCT [J].

GIOVANE, LM ;

BARCO, JW ;

YADAV, T ;

LAFLEUR, AL ;

MARR, JA ;

HOWARD, JB ;

ROTELLO, VM .

JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (33) :8560-8561

[4] REVERSIBLE COVALENT ATTACHMENT OF C-60 TO A POLYMER SUPPORT [J].

GUHR, KI ;

GREAVES, MD ;

ROTELLO, VM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (13) :5997-5998

[5] ELECTROCHEMISTRY AND LANGMUIR TROUGH STUDIES OF C-60 AND C-70 FILMS [J].

JEHOULET, C ;

OBENG, YS ;

KIM, YT ;

ZHOU, FM ;

BARD, AJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (11) :4237-4247

[6]

LOY DA, 1993, J AM CHEM SOC, V115, P3977

[7] SOLID PHASE PEPTIDE SYNTHESIS .1. SYNTHESIS OF A TETRAPEPTIDE [J].

MERRIFIELD, RB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (14) :2149-&

[8]

ROTELLO VM, 1993, TETRAHEDRON LETT, P1561

[9] FULLERENE-DOPED POLYSILANE PHOTOCONDUCTOR [J].

WANG, Y ;

WEST, R ;

YUAN, CH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (09) :3844-3845

[10]

WUDL F, 1992, ACS SYM SER, V481, P161

← 1 2 →