ELECTEON SPIN RESONANCE OF STABLE AROMATIC RADICAL INTERMEDIATES IN PYROLYSIS

被引：35

作者：

LEWIS, IC

SINGER, LS

机构：

[1] Union Carbide Corporation, Carbon Products Division, Parma Technical Center, Parma

来源：

CARBON | 1969年 / 7卷 / 01期

关键词：

D O I：

10.1016/0008-6223(69)90009-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This paper presents the results of electron spin resonance measurements on several types of stable aromatic free radicals suspected as intermediates in carbonization. The radicals studied include phenalenyl, 1-methylphenalenyl, 1-phenylphenalenyl, fluorenyl, 9-phenylfluorenyl, and biphenyleneallyl. The radicals all show remarkable stability at high temperatures. For at least a limited group of compounds, a correlation appears to exist between the planarity of free radical intermediates formed during carbonization and the degree of order of the final graphites. © 1969.

引用

页码：93 / &

共 16 条

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