MOSSBAUER SPECTRA OF SOME BIS(N,N-DISUBSTITUTED DITHIOCARBAMATO)IRON(3) COMPOUNDS

被引:45
作者
EPSTEIN, LM
STRAUB, DK
机构
[1] Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania
关键词
D O I
10.1021/ic50073a030
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Mössbauer spectra were obtained on several iron(III) complexes of the general formula (R2NCS2)2FeX, where X represents Cl, Br, I, NCS, or C6F5CO2. There was no systematic variation in the isomer shifts which were all close to 0.64 mm/sec (with respect to sodium nitroprusside) at room temperature. The quadrupole splitting ranged from 2.4 to 3.0 mm/sec and showed systematic variation with X with little or no dependence on R. © 1969, American Chemical Society. All rights reserved.
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页码:560 / &
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