THE INTRODUCTION OF SCF3 INTO AROMATIC SUBSTRATES USING CUSCF3 AND ALUMINA-SUPPORTED CUSCF3

被引：71

作者：

CLARK, JH

JONES, CW

KYBETT, AP

MCCLINTON, MA

MILLER, JM

BISHOP, D

BLADE, RJ

机构：

[1] BROCK UNIV,DEPT CHEM,ST CATHARINES L2S 3A1,ONTARIO,CANADA

[2] BDH LTD,POOLE BH12 4NN,DORSET,ENGLAND

[3] WELLCOME FDN LTD,BERKHAMSTED HP4 2DY,ENGLAND

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1990年 / 48卷 / 02期

基金：

英国惠康基金;

关键词：

D O I：

10.1016/S0022-1139(00)80437-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Trifluoromethylthiocopper(I) has been readily prepared from the silver analogue, using a metathetical reaction with copper(I) bromide. Homogeneous CuSCF3 and the supported reagent CuSCF3-alumina have been compared in their reactivity towards aryl iodides, in order to form trifluoromethylaryl sulphides in good yields. © 1990.

引用

页码：249 / 255

页数：7

共 18 条

[1] ARYL FLUOROALKYL SULFIDES .2. PREPARATION BY CONDENSATION OF TRIFLUOROMETHANESULFENYL CHLORIDE WITH AROMATIC SYSTEMS
ANDREADES, S
SHEPPARD, WA
HARRIS, JF
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1964, 29 (04) : 898 - &
[2] Banks R. E., 1979, ORGANOFLUORINE CHEM
[3] REVERSE HALOGENATION USING SUPPORTED COPPER(I) IODIDE
CLARK, JH
JONES, CW
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (18) : 1409 - 1410
[4] CLARK JH, 1989, J CHEM RES-S, P238
[5] SUPPORTED CYANIDES - THE INTERACTION OF POTASSIUM CYANIDE WITH HIGH SURFACE-AREA INORGANIC SUPPORT MATERIALS AND THE DEVELOPMENT OF HIGHLY REACTIVE CYANIDE REAGENTS
CLARK, JH
DUKE, CVA
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (08) : 1330 - 1332
[6] THE DIRECT TRIFLUOROMETHYLATION OF ARYL CHLORIDES USING BURTON REAGENT
CLARK, JH
MCCLINTON, MA
BLADE, RJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (10) : 638 - 639
[7] THE SYNTHESIS OF ORGANOFLUORINE COMPOUNDS USING POTASSIUM FLUORIDE-TETRAPHENYLPHOSPHONIUM BROMIDE SYSTEMS
CLARK, JH
MACQUARRIE, DJ
[J]. TETRAHEDRON LETTERS, 1987, 28 (01) : 111 - 114
[8] CALCIUM FLUORIDE-SUPPORTED ALKALI-METAL FLUORIDES - NEW REAGENTS FOR NUCLEOPHILIC FLUORINE TRANSFER-REACTIONS
CLARK, JH
HYDE, AJ
SMITH, DK
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (10) : 791 - 793
[9] DICKEY JB, 1948, Patent No. 2436100
[10] TRIFLUOROMETHANETHIOLATE ION .2. NUCLEOPHILIC-SUBSTITUTION IN PENTAFLUOROPYRIDINE - SYNTHESIS AND CHARACTERISTICS OF TRIFLUOROMETHYLTHIO AND TRIFLUOROMETHYLSULPHONYL DERIVATIVES
DMOWSKI, W
HAAS, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1987, (10): : 2119 - 2124

← 1 2 →