AN HEXAGONAL COLUMNAR MESOPHASE IN HALF-DISK-SHAPED THALLIUM (I) COMPLEXES

被引:49
作者
BARBERA, J
CATIVIELA, C
SERRANO, JL
ZURBANO, MM
机构
[1] Facultad de Ciencias - ICMA Universidad de Zaragoza - CSIC, Zaragoza
关键词
D O I
10.1002/adma.19910031206
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Communication: The first example of a discotic thallium (I) metallomesogen is reported. The complex is formed by the association of two half-disk-shaped molecules (see figure) and the properties of the liquid crystalline material studied using DSC and X-ray diffraction. The materials, with varying numbers of alkyl groups bonded to the central aromatic cores, are also compared with the previously known copper analogues.
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页码:602 / 605
页数:4
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