ELECTROLYTIC EQUIPMENT FOR REDUCTIONS IN LIQUID-AMMONIA

被引：12

作者：

COMBELLAS, C

MARZOUK, H

THIEBAULT, A

机构：

[1] Laboratoire de Chimie et Electrochimie des Matériaux Moléculaires, ESPCI, Paris Cedex 05, 75231, 10, rue Vauquelin

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1991年 / 21卷 / 03期

关键词：

D O I：

10.1007/BF01052581

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

We have developed static and circulating electrolytic equipment for liquid ammonia (or low molecular weight amines) to perform reductions of compounds bearing at least one reducible group. The equipment contains undivided electrochemical cells including consumable magnesium anodes. Birch and Bouveault-Blanc reductions are performed with substrate weight percents up to 10%. A circulating electrolytic cell working at room temperature is described which may be adaptable to large scale production.

引用

页码：267 / 275

页数：9

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