MOBILITIES OF METAL CLUSTER IONS - ALUMINUM AND THE ELECTRONIC SHELL-MODEL

被引：62

作者：

JARROLD, MF ^{[1
]}

BOWER, JE ^{[1
]}

机构：

[1] AT&T BELL LABS,MURRAY HILL,NJ 07974

来源：

JOURNAL OF CHEMICAL PHYSICS | 1993年 / 98卷 / 03期

关键词：

D O I：

10.1063/1.464167

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The mobilities of size-selected aluminum cluster ions containing 5-73 atoms have been measured using injected ion drift tube techniques. The mobilities show an apparent correlation with the electronic shell model: Clusters close to the electronic shell closings have enhanced mobilities. A structural transition appears to be associated with the shell closing with 138 valence electrons. Structural isomers were identified for a few clusters at low temperatures. But with only one exception (Al45+) the annealing temperatures of these isomers are below room temperature.

引用

页码：2399 / 2407

页数：9

共 45 条

[1] ELECTRONIC AND GEOMETRIC STRUCTURE IN SILVER CLUSTERS
ALAMEDDIN, G
HUNTER, J
CAMERON, D
KAPPES, MM
[J]. CHEMICAL PHYSICS LETTERS, 1992, 192 (01) : 122 - 128
[2] [Anonymous], 1973, MOBILITY DIFFUSION I
[3] [Anonymous], 1972, UNIMOLECULAR REACTIO
[4] SELF-CONSISTENT CALCULATION OF THE ELECTRONIC-STRUCTURE OF SMALL JELLIUM SPHERES
BECK, DE
[J]. SOLID STATE COMMUNICATIONS, 1984, 49 (04) : 381 - 385
[5] BLOOMFIELD L, COMMUNICATION
[6] VAN DER WAALS VOLUMES + RADII
BONDI, A
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) : 441 - +
[7] ELECTRONIC-STRUCTURE AND BINDING-ENERGIES OF ALUMINUM CLUSTERS
CHENG, HP
BERRY, RS
WHETTEN, RL
[J]. PHYSICAL REVIEW B, 1991, 43 (13): : 10647 - 10653
[8] ELECTRONIC SHELL STRUCTURE IN SIMPLE METAL-CLUSTERS
CHOU, MY
COHEN, ML
[J]. PHYSICS LETTERS A, 1986, 113 (08) : 420 - 424
[9] ELLIPSOIDAL SHELL STRUCTURE IN FREE-ELECTRON METAL-CLUSTERS
CLEMENGER, K
[J]. PHYSICAL REVIEW B, 1985, 32 (02): : 1359 - 1362
[10] PHYSICS OF METAL-CLUSTERS
COHEN, ML
CHOU, MY
KNIGHT, WD
DEHEER, WA
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (12) : 3141 - 3149

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