SELF-CONDENSATION OF 1-BROMO-2-NAPHTHOL - MECHANISM OF FORMATION OF A 1,4-DINAPHTHODIOXIN

被引:3
作者
FORLANI, L
LUGLI, A
NANNI, D
TODESCO, PE
机构
[1] Dipartimento di Chimica Organica 'A. Mangini', Università di Bologna, I-40136, Bologna
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1994年 / 06期
关键词
D O I
10.1039/p29940001291
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The reaction of 1-bromo-2-naphthol with its conjugated base (sodium 1-bromo-2-naphthoxide) affords 1-bromo-2'-hydroxy-2,1'-dinaphthyl ether and follows a second-order kinetic law. The bromo ether can be cyclised to a 1,4-dioxin derivative through a radical ipso-substitution reaction, predominantly. Some mechanistic implications are discussed.
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页码:1291 / 1293
页数:3
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