APPLICATION OF THE TRANSITION-STATE THEORY TO THE PYROLYSIS OF BIOMASS AND TARS

被引：34

作者：

FONT, R

GARCIA, AN

机构：

[1] Departamento de Ingenieria Quimica, Universidad de Alicante, Alicante

来源：

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 1995年 / 35卷 / 02期

关键词：

ACTIVATED COMPLEX; BIOMASS; ENTROPY; PYROLYSIS; REACTION ORDER; TARS; THERMAL DECOMPOSITION; TRANSITION STATE THEORY;

D O I：

10.1016/0165-2370(95)00916-8

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The application of the transition state theory to the pyrolysis of biomass and tars has been analyzed. Values of the specific surface of the solid, the length of the molecular unit involved in the decomposition and the solid density must be taken into account to calculate the entropy of the activated complex. Reaction orders different from unity in the thermal decomposition of solids are explained.

引用

页码：249 / 258

页数：10

共 25 条

[1]

AGRAWAL KA, 1988, ASTM STP, V997, P259

[2] DETERMINATION OF KINETIC PARAMETERS FOR PYROLYSIS OF CELLULOSE AND CELLULOSE TREATED WITH AMMONIUM PHOSPHATE BY DIFFERENTIAL THERMAL ANALYSIS AND THERMAL GRAVIMETRIC ANALYSIS [J].