PLATINUM-CARBON BOND STRENGTH IN PT(PPH3)2(CH3)I

被引：11

作者：

MORTIMER, CT ^{[1
]}

WILKINSON, MP ^{[1
]}

PUDDEPHATT, RJ ^{[1
]}

机构：

[1] UNIV LIVERPOOL,DEPT CHEM,LIVERPOOL L69 3BX,LANCASHIRE,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 165卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)94328-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The enthalpies of reaction 1-3 have been determined {A figure is presented} as ΔH(1) = -176.6 ± 5.4, ΔH(2) = -107.8 ± 6.0, and ΔH(3) = -78.9 ± 2.0 kJ mol-1. The bond dissociation energy difference D1(PtCH3) - D1(PtI) = +6 ± 5 kJ mol-1 is calculated, which indicates that the two bonds have very similar strengths. © 1979.

引用

页码：265 / 267

页数：3

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