PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF [NI(DPDT)(2)], A NOVEL NICKEL 1,2-DITHIOLENE COMPLEX (H(2)DPDT=6-METHYLENE-1,4-DITHIEPIN-2,3-DITHIOL)

被引：13

作者：

CHARLTON, A

UNDERHILL, AE

MALIK, KMA

HURSTHOUSE, MB

JORGENSEN, T

BECHER, J

机构：

[1] UNIV COLL N WALES,DEPT CHEM,BANGOR LL57 2UW,GWYNEDD,WALES

[2] UNIV WALES COLL CARDIFF,SCH CHEM & APPL CHEM,CARDIFF CF1 3TB,S GLAM,WALES

[3] ODENSE UNIV,INST KEMISK,DK-5230 ODENSE M,DENMARK

来源：

SYNTHETIC METALS | 1995年 / 68卷 / 03期

关键词：

CRYSTAL; STRUCTURE; NICKEL; DITHIOLENE;

D O I：

10.1016/0379-6779(94)02306-J

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

[Ni(dpdt)(2)] (H(2)dpdt=6-methylene-1,4-dithiepin-2,3-dithiol) has been prepared from [NBu(4)][Ni(dpdt)(2)], using both chemical and electrochemical methods. Electrical conduction studies indicate that the compound is a semiconductor (sigma(RT)=10(-5) S cm(-1)). The X-ray crystal structure of [Ni(dpdt)(2)] is reported.

引用

页码：221 / 226

页数：6

共 20 条

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BROSSARD L, 1986, CR ACAD SCI II, V302, P205

[2] MOLECULAR-METALS AND SUPERCONDUCTORS DERIVED FROM METAL-COMPLEXES OF 1,3-DITHIOL-2-THIONE-4,5-DITHIOLATE (DMIT) [J].