A NOVEL PHOSPHORUS CHALCOGENIDE - P2SE5

被引：14

作者：

BLACHNIK, R ^{[1
]}

BALDUS, HP ^{[1
]}

LONNECKE, P ^{[1
]}

TATTERSHALL, BW ^{[1
]}

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 05期

关键词：

D O I：

10.1002/anie.199106051

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A phosphorus/selenium ratio of 2:5 does not necessarily mean that P2Se5 is also a structural analogue of P4O10. As shown on the right, the phosphorus atoms in P2Se5 are threefold coordinated. They are joined through one mono- and two diselenide bridges. In short, a large ratio of selenium in the system phosphorus-selenium does not lead automatically to an increase in the coordination number at phosphorus.

引用

页码：605 / 607

页数：3

共 12 条

[1]

BERZELIUS JJ, 1942, GMELINS HDB ANORGANI, P244

[2] P3SE4I-5-IODO-2,3,6,7-TETRASELENA-1,4,5-TRIPHOSPHABICYCLO[221]HEPTAN, A NEW PHOSPHORUS SELENA IODIDE [J].

BLACHNIK, R ;

BUCHMEIER, W ;

SCHNEIDER, C ;

WICKEL, U .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1987, 42 (01) :47-51

[3]

BLACHNIK R, 1984, Z NATURFORSCH B, V39, P778

[4]

HUNT GW, 1971, INORG CHEM, V10, P1935

[5] THE CRYSTAL STRUCTURE OF P4SE3 [J].

KEULEN, E ;

VOS, A .

ACTA CRYSTALLOGRAPHICA, 1959, 12 (04) :323-329

[6] CHEMISTRY OF PHOSPHORUS PENTASELENIDE .I. ITS REACTION WITH ALCOHOLS [J].

KUDCHADKER, MV ;

ZINGARO, RA ;

IRGOLIC, KJ .

CANADIAN JOURNAL OF CHEMISTRY-BACK YEAR, 1968, 46 (08) :1415-+

[7] THE CRYSTAL STRUCTURE OF P4S3 [J].

LEUNG, YC ;

WASER, J ;

VANHOUTEN, S ;

VOS, A ;

WIEGERS, GA ;

WIEBENGA, EH .

ACTA CRYSTALLOGRAPHICA, 1957, 10 (09) :574-582

[8] STUDY OF AMORPHOUS DOMAIN FOR SYSTEM P-SE-S - SYNTHESIS AND CHARACTERIZATION OF AMORPHOUS COMPOUND P4SE10 [J].

MONTEIL, Y ;

VINCENT, H .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1977, 428 (01) :259-268

[9] CRYSTAL AND MOLECULAR STRUCTURE OF TETRAPHOSPHORUS TRISELENODIIODIDE [J].

PENNEY, GJ ;

SHELDRIC.GM .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1970, B 26 (DEC15) :2092-&

[10] THE STRUCTURE OF PHOSPHORUS-SELENIUM GLASSES .1. CONCENTRATION-DEPENDENCE OF THE SHORT-RANGE AND INTERMEDIATE-RANGE ORDER [J].

PRICE, DL ;

MISAWA, M ;

SUSMAN, S ;

MORRISON, TI ;

SHENOY, GK ;

GRIMSDITCH, M .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1984, 66 (03) :443-465

← 1 2 →