THE REDUCTIVE CHEMISTRY OF NICKEL HYDROPORPHYRINS .3. FACILE FORMATION OF HEXAHYDROPORPHYRIN COMPLEXES BY REDUCTION OF OCTAETHYLISOBACTERIOCHLORINNICKEL(II)

被引：15

作者：

LAHIRI, GK ^{[1
]}

STOLZENBERG, AM ^{[1
]}

机构：

[1] W VIRGINIA UNIV,DEPT CHEM,POB 6045,MORGANTOWN,WV 26506

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 03期

关键词：

D O I：

10.1002/anie.199304291

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Under extremely mild conditions (room temperature) the hexahydroporphyrin 2 isomerizes to its tautomer 3. Complex 2 is the first metal complex with a 2,3,7,8,15,23-hexahydroporphyrin as ligand and is synthesized from 1 by reduction with sodium amalgam. [GRAPHICS]

引用

页码：429 / 432

页数：4

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