CATIONIC DITHIOLENE METAL-COMPLEXES WITH 5,6-DIHYDRO-1,4-DITHIN-2,3-DITHIOL - HIGHLY CONDUCTING METAL-COMPLEX ANALOGS OF BEDT-TTF SALTS

被引：33

作者：

YAGUBSKII, EB

KOTOV, AI

BURAVOV, LI

KHOMENKO, AG

SHKLOVER, VE

NAHAPETYAN, SS

STRUCHKOV, YT

VETOSHKINA, LV

UKHIN, LY

机构：

[1] AN NESMEYANOV ORGANOELEMENT CPDS INST,MOSCOW,USSR

[2] ROSTOV DON STATE UNIV,INST PHYS & ORGAN CHEM,ROSTOV,USSR

来源：

SYNTHETIC METALS | 1990年 / 35卷 / 03期

关键词：

D O I：

10.1016/0379-6779(90)90211-3

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A new class of highly conducting compounds (cationic dithiolene metal complexes of Ni and Au with 5,6-dihydro-1,4-dithiin-2,3-dithiol (DDDT), which are metal complex analogues of BEDT-TTF salts) has been obtained. The crystal structure of one of the representatives of this class, [Ni(DDDT)2]3(BF4)2, has been determined. The crystal contains stacks of [Ni(DDDT)2] cations with shortened intra- and interstack S·S contacts. The conductivity of these complexes at room temperature is 1 - 50 ohm-1 cm-1. © 1990.

引用

页码：271 / 280

页数：10

共 21 条

[1]

BROSSARD L, 1988, SYNTHETIC MET, V27, pB157, DOI 10.1016/0379-6779(88)90139-7

[2]

Buranov LJ, 1971, PRIB TEKH EKSP, V2, P171

[3]

BURAVOV LI, 1985, ZH EKSP TEOR FIZ+, V88, P2185

[4]

BURAVOV LI, 1989, ZH EKSP TEOR FIZ+, V95, P322

[5]

GERR RG, 1983, KRISTALLOGRAFIYA+, V28, P1029

[6]

KATO R, 1988, SYNTHETIC MET, V27, pB359, DOI 10.1016/0379-6779(88)90169-5

[7] CRYSTAL-STRUCTURE AND MOLECULAR-STRUCTURE OF NEUTRAL NICKEL BIS(5,6-DIHYDRO-1,4-DITHIIN-2,3-DITHIOLATE), NI(DDDT)2 [J].

KIM, H ;

KOBAYASHI, A ;

SASAKI, Y ;

KATO, R ;

KOBAYASHI, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (02) :579-581

[8] THE 1ST MOLECULAR SUPERCONDUCTOR BASED ON PI-ACCEPTOR MOLECULES AND CLOSED-SHELL CATIONS, [(CH3)4N][NI(DMIT)2]2, LOW-TEMPERATURE X-RAY STUDIES AND SUPERCONDUCTING TRANSITION [J].

KOBAYASHI, A ;

KIM, H ;

SASAKI, Y ;

KATO, R ;

KOBAYASHI, H ;

MORIYAMA, S ;

NISHIO, Y ;

KAJITA, K ;

SASAKI, W .

CHEMISTRY LETTERS, 1987, (09) :1819-1822

[9]

LAUKHIN VN, 1985, JETP LETT+, V41, P81

[10]

MERZHANOV VA, 1985, JETP LETT, V41, P146

← 1 2 3 →