CONCERNING THE MECHANISM OF GIF OXIDATIONS OF CYCLOALKANES

被引：45

作者：

KNIGHT, C ^{[1
]}

PERKINS, MJ ^{[1
]}

机构：

[1] UNIV LONDON ROYAL HOLLOWAY & BEDFORD NEW COLL,DEPT CHEM,EGHAM TW20 0EX,SURREY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 14期

关键词：

D O I：

10.1039/c39910000925

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxygen atom of cyclodecanone, formed by oxidation of cyclodecane using FeCl3-H2O2 in pyridine-acetic acid, is largely derived from molecular oxygen: taken in conjunction with results of radical-trapping experiments, this supports a free-radical mechanism for the hydrocarbon activation.

引用

页码：925 / 927

页数：3

共 10 条

[1] MECHANISM OF THE SELECTIVE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS BY GIF SYSTEMS - RELATIONSHIP WITH METHANE MONOOXYGENASE [J].

BARTON, DHR ;

CSUHAI, E ;

DOLLER, D ;

OZBALIK, N ;

BALAVOINE, G .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1990, 87 (09) :3401-3404

[2] DETECTION OF CYCLOHEXYL HYDROPEROXIDE AS AN INTERMEDIATE IN GIF TYPE OXIDATION OF CYCLOHEXANE TO CYCLOHEXANONE USING C-13 NMR-SPECTROSCOPY [J].

BARTON, DHR ;

CSUHAI, E ;

DOLLER, D ;

BALAVOINE, G .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (24) :1787-1789

[3] FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .14. FURTHER-STUDIES ON THE MECHANISM OF GIF-TYPE SYSTEMS [J].

BARTON, DHR ;

HALLEY, F ;

OZBALIK, N ;

SCHMITT, M ;

YOUNG, E ;

BALAVOINE, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (18) :7144-7149

[4]

BARTON DHR, 1986, NOUV J CHIM, V19, P386

[5] CRITICAL-REVIEW OF RATE CONSTANTS FOR REACTIONS OF HYDRATED ELECTRONS, HYDROGEN-ATOMS AND HYDROXYL RADICALS (.OH/.O-) IN AQUEOUS-SOLUTION [J].

BUXTON, GV ;

GREENSTOCK, CL ;

HELMAN, WP ;

ROSS, AB .

JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1988, 17 (02) :513-886

[6] SUPEROXIDE-DEPENDENT FORMATION OF HYDROXYL RADICALS FROM FERRIC-COMPLEXES AND HYDROGEN-PEROXIDE - AN EVALUATION OF 14 IRON CHELATORS [J].

GUTTERIDGE, JMC .

FREE RADICAL RESEARCH COMMUNICATIONS, 1990, 9 (02) :119-125

[7] A WATER-SOLUBLE, NITROSO-AROMATIC SPIN-TRAP [J].

KAUR, H ;

LEUNG, KHW ;

PERKINS, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (03) :142-143

[8] AROMATIC HYDROXYLATION OF PHENYLALANINE AS AN ASSAY FOR HYDROXYL RADICALS - APPLICATION TO ACTIVATED HUMAN-NEUTROPHILS AND TO THE HEME PROTEIN LEGHEMOGLOBIN [J].

KAUR, H ;

FAGERHEIM, I ;

GROOTVELD, M ;

PUPPO, A ;

HALLIWELL, B .

ANALYTICAL BIOCHEMISTRY, 1988, 172 (02) :360-367

[9] KINETICS OF DECOMPOSITION OF HYDROGEN-PEROXIDE CATALYZED BY FERRIC ETHYLENEDIAMINETETRAACETATE COMPLEX [J].

WALLING, C ;

PARTCH, RE ;

WEIL, T .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1975, 72 (01) :140-142

[10] POSITIVE HALOGEN COMPOUNDS .1. THE RADICAL CHAIN HALOGENATION OF HYDROCARBONS BY TERT-BUTYL HYPOCHLORITE [J].

WALLING, C ;

JACKNOW, BB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (23) :6108-6112

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