THE SYNTHESIS AND STRUCTURE OF SOME NEW SODALITES - THE LITHIUM HALOBERYLLOPHOSPHATES AND HALOBERYLLOARSENATES

被引：23

作者：

GIER, TE ^{[1
]}

HARRISON, WTA ^{[1
]}

STUCKY, GD ^{[1
]}

机构：

[1] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 09期

关键词：

D O I：

10.1002/anie.199111691

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Spherical cavities with included tetrahedral Li4Br units, which are surround by regularly arranged BeO4- and PO4-tetrahedra, are present in Li8Br2 (Be6P6O24) (picture on the right). This beryllophosphate with sodalite structure is accessible by hydrothermal synthesis and is further proof of the extensive structural chemistry of molecular sieves based on metals of main group 2. [GRAPHICS]

引用

页码：1169 / 1171

页数：3

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