REACTIONS OF 1,1-DISUBSTITUTED ALKENES WITH ACETOACETAMIDES AND MOLECULAR-OXYGEN IN THE PRESENCE OF MANGANESE(III) ACETATE

被引：21

作者：

QIAN, CY ^{[1
]}

NISHINO, H ^{[1
]}

KUROSAWA, K ^{[1
]}

机构：

[1] KUMAMOTO UNIV, FAC SCI, DEPT CHEM, KUROKAMI 2-39-1, KUMAMOTO 860, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 12期

关键词：

D O I：

10.1246/bcsj.64.3557

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of 1,1-disubstituted ethenes with acetoacetamide or N-substituted acetoacetamides, and molecular oxygen in the presence of manganese(III) acetate gave a mixture of c-4- and t-4-carbamoyl-3-methyl-1,2-dioxan-r-3-ols in good yields. Effects of substituents in the alkenes as well as in the carbamoyl group in the acetoacetamides were observed. Stereochemistry and the reactivity of the 4-carbamoyl-3-methyl-1,2-dioxan-3-ols are discussed.

引用

页码：3557 / 3564

页数：8

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