SYNTHESIS AND STRUCTURE OF [NI(PTERT-BU6)] AND [NI5(PTERT-BU)6(CO)5] AND CALCULATIONS ON THE ELECTRONIC-STRUCTURE OF [NI(PTERT-BU)6] AND (PR)6, R = TERT-BU, ME

被引：28

作者：

AHLRICHS, R ^{[1
]}

FENSKE, D ^{[1
]}

OESEN, H ^{[1
]}

SCHNEIDER, U ^{[1
]}

机构：

[1] UNIV KARLSRUHE, INST ANORGAN CHEM, W-7500 KARLSRUHE, GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 03期

关键词：

D O I：

10.1002/anie.199203231

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A planar P6‐ring, with a Ni atom located at its center, characterizes the novel complex, [Ni(PtBu)6] (1), shown here. This NiP6 complex is formed upon reaction of (PtBu)3 with NiCl2 and P(SiMe3)3. In contrast, reaction of (PtBu)3 with [Ni(CO)4] affords the pentanuclear cluster [Ni5(PtBu)3(P3tBu3)‐(CO)5]. (Figure Presented.) Copyright © 1992 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：323 / 326

页数：4

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