THEORY OF CYCLIC VOLTAMMETRY FOR QUASI-REVERSIBLE ELECTRODEPOSITION REACTIONS WITH INSOLUBLE PRODUCTS

被引：8

作者：

AVACA, LA ^{[1
]}

KAUFMANN, S ^{[1
]}

KONTTURI, K ^{[1
]}

MURTOMAKI, L ^{[1
]}

SCHIFFRIN, DJ ^{[1
]}

机构：

[1] UNIV LIVERPOOL,DEPT CHEM,LIVERPOOL L69 3BX,ENGLAND

来源：

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1993年 / 97卷 / 01期

关键词：

CYCLIC VOLTAMMETRY; ELECTROCHEMISTRY; ELECTRODE KINETICS; RATE CONSTANTS;

D O I：

10.1002/bbpc.19930970114

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Matsuda theory of cyclic voltammetry for quasi-reversible reactions is extended to metal dissolution and electrodeposition. Kinetic data can be conveniently obtained from the measurement of peak potentials and peak currents as a function of sweep rate and switching potentials. As an example, the rate constant for the Zn(s)/Zn++(aq) couple has been measured to be k0 = 7.5 . 10(-7) cm s-1.

引用

页码：70 / 76

页数：7