SYNTHESIS OF THE CYCLIC SYSTEM OF LINEAR AZA-TRIQUINANE BY 3 CASCADE RADICAL CYCLIZATIONS

被引：12

作者：

BOATE, D

FONTAINE, C

GUITTET, E

STELLA, L

机构：

[1] UNIV AIX MARSEILLE 3,FAC SCI ST JEROME,CNRS,CHIM ORGAN LAB,AVE NORMANDIE NIEMEN,F-13397 MARSEILLE 20,FRANCE

[2] INST CHIM SUBST NAT,CNRS,F-91198 GIF SUR YVETTE,FRANCE

来源：

TETRAHEDRON | 1993年 / 49卷 / 37期

关键词：

CASCADE RADICAL CYCLIZATION; N-CHLOROALKENYLAMINE; AZA-TRIQUINANE;

D O I：

10.1016/S0040-4020(01)81922-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of the acyclic allyl-octa-4,7-dienyl N-chloroamine 5 by titanium trichloride induces a chain process including three consecutive regio- and stereo-selective homolytic cyclisations. As a result of these selectivities, the main product of the reaction is an original linear cis-syn-cis aza-triquinane, the structure of which was assigned by high field (400 MHz) Nuclear Magnetic Resonance study.

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页码：8397 / 8406

页数：10

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