DENSITIES, VISCOSITIES, AND CONDUCTIVITIES OF MIXTURES OF SELECTED ORGANIC COSOLVENTS WITH THE LEWIS BASIC ALUMINUM-CHLORIDE PLUS 1-METHYL-3-ETHYLIMIDAZOLIUM CHLORIDE MOLTEN-SALT

被引：65

作者：

PERRY, RL ^{[1
]}

JONES, KM ^{[1
]}

SCOTT, WD ^{[1
]}

LIAO, Q ^{[1
]}

HUSSEY, CL ^{[1
]}

机构：

[1] UNIV MISSISSIPPI, DEPT CHEM, UNIVERSITY, MS 38677 USA

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1995年 / 40卷 / 03期

关键词：

D O I：

10.1021/je00019a017

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The densities, kinematic viscosities, and specific conductances of mixtures of the organic cosolvents acetonitrile, benzene, and dichloromethane with the Lewis basic room-temperature chloroaluminate molten salt aluminum chloride + 1-methyl-3-ethylimidazolium chloride(AlCl3 + MeEtimCl) were determined at 25 degrees C. Cosolvents were added to melts containing 49.00 and 44.40 mol % (m/o) AlCl3. Polynomial equations were fitted to the results as a function of the mass fraction of the cosolvent. The addition of relatively small amounts of these cosolvents causes a significant decrease in viscosity and a large increase in the conductivity of basic melts.

引用

页码：615 / 619

页数：5

共 14 条

[1]

BRANSTEIN J, 1971, J CHEM EDUC, V48, P52

[2]

CARLINRT, 1994, CHEM NONAQUEOUS SOLU, P277

[3] CONDUCTANCE OF ALKALI HALIDES .12. SODIUM AND POTASSIUM CHLORIDES IN WATER AT 25 DEGREES [J].