NATURAL ABUNDANCE O-17 NMR-STUDIES OF THIOL ESTERS AND RELATED ANALOGS

被引：5

作者：

BOYKIN, DW

机构：

[1] Department of Chemistry, Georgia State University, Atlanta

来源：

SPECTROSCOPY LETTERS | 1990年 / 23卷 / 09期

关键词：

170 NMR spectroscopy; esters; thiol esters;

D O I：

10.1080/00387019008054487

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Natural abundance 170 NMR data for a series of thiol esters and related analogs are reported. The carbonyl signal of the thiol esters range from 463 ppm to 514 ppm; these values are downfield of their oxygen analogs by ca. 150 ppm. A linear relationship between the 170 NMR chemical shift of the thio-compounds and their oxo-analogs is observed. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

收藏

页码：1133 / 1140

页数：8

相关论文

共 19 条

[1] O-17 NMR-SPECTROSCOPY - EFFECT OF SUBSTITUENTS ON CHEMICAL-SHIFTS FOR PARA-SUBSTITUTED BENZOIC-ACIDS, METHYL BENZOATES, CINNAMIC-ACIDS AND METHYL CINNAMATES [J].

BALAKRISHNAN, P ;

BAUMSTARK, AL ;

BOYKIN, DW .

ORGANIC MAGNETIC RESONANCE, 1984, 22 (12) :753-756

[2] O-17 NMR-SPECTROSCOPY - TORSION ANGLE RELATIONSHIPS IN ARYL CARBOXYLIC ESTERS, ACIDS, AND AMIDES [J].

BAUMSTARK, AL ;

BALAKRISHNAN, P ;

DOTRONG, M ;

MCCLOSKEY, CJ ;

OAKLEY, MG ;

BOYKIN, DW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (04) :1059-1062

[3]

BAUMSTARK AL, IN PRESS 17O NMR SPE, pCH3

[4]

BOYKIN DW, 1989, HETEROCYCLES, V29, P301

[5] NATURAL ABUNDANCE O-17 NMR-STUDY OF ALPHA-SUBSTITUTED METHYL ACETATES [J].

BOYKIN, DW ;

SUBRAMANIAN, TS ;

BAUMSTARK, AL .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1989, 45 (03) :335-338

[6] O-17 NMR-SPECTROSCOPY - ASSESSMENT OF STERIC PERTURBATION OF STRUCTURE IN ORGANIC-COMPOUNDS [J].

BOYKIN, DW ;

BAUMSTARK, AL .

TETRAHEDRON, 1989, 45 (12) :3613-3651

[7]

Bruice TC, 1966, BIOORG MECH, P259

[8] CORRELATION OF O-17 NMR AND O-17 NQR DATA FOR SOME AROMATIC CARBONYL-COMPOUNDS [J].

CHENG, CP ;

LIN, SC ;

SHAW, GS .

JOURNAL OF MAGNETIC RESONANCE, 1986, 69 (01) :58-67

[9]

DELSETH C, 1980, HELV CHIM ACTA, V63, P498, DOI 10.1002/hlca.19800630222

[10] C-13 NUCLEAR MAGNETIC-RESONANCE STUDY OF THIOL ESTERS [J].

HALL, CM ;

WEMPLE, J .

JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (12) :2118-2123