CORRELATION BETWEEN THEORY AND EXPERIMENT IN ELECTRON-TRANSFER REACTIONS IN PROTEINS - ELECTRONIC COUPLINGS IN MODIFIED CYTOCHROME-C AND MYOGLOBIN DERIVATIVES

被引：92

作者：

SIDDARTH, P

MARCUS, RA

机构：

[1] CALTECH,ARTHUR AMOS NOYES LAB CHEM PHYS,PASADENA,CA 91125

[2] UNIV BRITISH COLUMBIA,DEPT BIOCHEM,VANCOUVER V6T 1Z3,BC,CANADA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1993年 / 97卷 / 50期

关键词：

D O I：

10.1021/j100152a008

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The artificial intelligence-superexchange method of estimating the long-range electronic coupling in proteins that we have developed previously is used to study electron-transfer reactions in Ru-modified cytochrome c and myoglobin derivatives. Good correlations between theoretical and experimental mte constants are obtained using the present method. Amino acid paths for electron transfer are analyzed.

引用

收藏

页码：13078 / 13082

页数：5

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