PREFERENTIAL SOLVATION AND ROLE OF SOLVENT IN KINETICS EXAMPLES FROM LIGAND SUBSTITUTION-REACTIONS

被引：54

作者：

LANGFORD, CH ^{[1
]}

TONG, JPK ^{[1
]}

机构：

[1] CARLETON UNIV,DEPT CHEM,MET IONS GRP,OTTAWA K1S 5B6,ONTARIO,CANADA

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 1977年 / 10卷 / 07期

关键词：

D O I：

10.1021/ar50115a005

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：258 / 264

页数：7

共 39 条

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[4] PREFERENTIAL SOLVATION AND MECHANISMS OF THERMAL AND PHOTOCHEMICAL SOLVOLYSIS OF HEXATHIOCYANATOCHROMATE(3) ION IN ACETONITRILE-WATER MIXTURES
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[5] BLOOR EG, 1968, CAN J CHEM, V46, P4325
[6] CALDIN EF, 1974, J SOLUTION CHEM, V2, P176
[7] STRUCTURE OF 2ND COORDINATION SPHERE OF TRANSITION-METAL COMPLEXES .5. NUCLEAR MAGNETIC-RESONANCE T-1 MEASUREMENTS
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[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1976, 54 (08): : 1332 - 1340
[8] INFLUENCE OF ANIONIC INNER-SPHERE SUBSTITUENTS ON KINETICS OF TERNARY COMPLEX-FORMATION OF NICKEL(II) IN ACETONITRILE AS SOLVENT - OPPOSING EFFECTS OF SOLVENT LABILIZATION AND OUTER-SPHERE DESTABILIZATION
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[J]. INORGANIC CHEMISTRY, 1976, 15 (02) : 400 - 405
[9] BINARY AND TERNARY COMPLEX-FORMATION OF NICKEL(II) IN METHANOL - FURTHER EVIDENCE FOR OUTER-SPHERE STABILIZATION AND OTHER FACTORS CONTRIBUTING TO LIGAND SUBSTITUTION KINETICS IN NON-AQUEOUS SOLVENTS
COETZEE, JF
GILLES, DM
[J]. INORGANIC CHEMISTRY, 1976, 15 (02) : 405 - 408
[10] LIGAND SUBSTITUTION KINETICS OF NICKEL(II) ION IN 2-PROPRANOL AND ISOBUTYRONITRILE AS SOLVENTS - INFLUENCE OF STERIC CROWDING IN INNER SPHERE AND OF OTHER FACTORS
COETZEE, JF
KARAKATSANIS, CG
[J]. INORGANIC CHEMISTRY, 1976, 15 (12) : 3112 - 3114

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