SYNTHESIS OF STEREOCHEMICAL SYSTEMS WITH SILICON (OR GERMANIUM PHOSPHORUS BOND

被引：7

作者：

DUBAC, J ^{[1
]}

CAVEZZAN, J ^{[1
]}

MAZEROLLES, P ^{[1
]}

ESCUDIE, J ^{[1
]}

COURET, C ^{[1
]}

SATGE, J ^{[1
]}

机构：

[1] UNIV TOULOUSE 3,CHIM ORGAN MINERAUX LAB,CNRS,EQUIPE RECH 829,F-31077 TOULOUSE,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 174卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)85591-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Starting from geometrical isomers of 1,2-dimethylsila-(or germa-)cyclopentane, the first stereochemical systems containing a SiP (or GeP) bond, permitting the stereochemical study of the reaction process at the level of the heteroatom (Si, Ge), were synthesized. The structural analysis of configurationally stable 1-diethylphosphino-1,2-dimethylsila(or germa)cyclopentane is solved from 1H, 13P and 13C NMR data. A chemical method to prepare the desired geometric isomer of 1,2-dimethylsilacyclopentane is also described. © 1979.

引用

页码：263 / 274

页数：12

共 45 条

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