HOLE-BURNING AND PHOSPHORESCENCE LINE-NARROWING OF TRIPLET PI-PI-STAR STATE IN GLASSY MATRICES

被引：11

作者：

RIESEN, H

KRAUSZ, E

机构：

[1] Research School of Chemistry, The Australian National University, Canberra, ACT 2601

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 182卷 / 3-4期

关键词：

D O I：

10.1016/0009-2614(91)80213-H

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The low-temperature hole-burning spectra of the triplet pi-pi* state of coronene in 1-bromobutane:ethyliodide 4:1 (v/v) and 5-bromoacenaphthene and 2-iodoquinoline in 1-bromobutane are reported. The coronene system is unique in showing distinct sideholes. The lack of sideholes in the other two systems is attributed to a noncorrelation of the zero-field splitting within the probed isoenergetic component of the inhomogeneous distribution. This aspect is further pursued by phosphorescence-line-narrowing experiments for the 2-iodoquinoline/1-bromobutane system in magnetic fields up to 0.83 T.

引用

页码：266 / 270

页数：5

共 15 条

[1] POLARIZATIONS AND ASSIGNMENTS OF TRANSITIONS - METHOD OF PHOTOSELECTION
ALBRECHT, AC
[J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1961, 6 (01) : 84 - &
[2] APPEARANCE OF FINE-STRUCTURE IN PHOSPHORESCENCE SPECTRA OF ORGANIC-MOLECULES IN SOLID-SOLUTIONS UNDER T1]-S-0 LASER EXCITATION
ALSHITS, EI
PERSONOV, RI
KHARLAMOV, BM
[J]. CHEMICAL PHYSICS LETTERS, 1976, 40 (01) : 116 - 126
[3] THE TEMPERATURE-DEPENDENCE OF PHOSPHORESCENCE LINES IN GLASSY MATRICES
FUNFSCHILLING, J
ZSCHOKKEGRANACHER, I
[J]. CHEMICAL PHYSICS LETTERS, 1984, 110 (03) : 315 - 318
[4] OBSERVATION OF MULTIPLET STRUCTURE IN LOW-FIELD MAGNETIC RESONANCE SPECTRA OF TRIPLET STATES OF ORIENTED AROMATIC HYDROCARBONS
GERKIN, RE
WINER, AM
[J]. JOURNAL OF CHEMICAL PHYSICS, 1967, 47 (07) : 2504 - &
[5] KHARLAMOV RM, 1984, ZH EKSP TEOR FIZ+, V60, P428
[6] PHOSPHORESCENCE AND ZERO-FIELD OPTICALLY DETECTED MAGNETIC-RESONANCE STUDIES OF THE LOWEST EXCITED TRIPLET-STATES OF ORGANOMETALLIC DIIMINE COMPLEXES .1. [RH(BPY)3]3+ AND [RH(PHEN)3]3+
KOMADA, Y
YAMAUCHI, S
HIROTA, N
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (24) : 6425 - 6430
[7] LEE HWH, 1985, J CHEM PHYS, V82, P3948, DOI 10.1063/1.448887
[8] HEAVY-ATOM EFFECT AND MAGNETIC-FIELD EFFECTS IN PHOSPHORESCENCE HOLE BURNING
LIN, SX
FUNFSCHILLING, J
ZSCHOKKEGRANACHER, I
[J]. JOURNAL OF LUMINESCENCE, 1990, 46 (05) : 301 - 309
[9] McGlynn S. P., 1969, MOL SPECTROSCOPY TRI
[10] MOERNER WE, 1989, PERSISTENT SPECTRAL

← 1 2 →