CATIONIC AND NEUTRAL NITROSAMIDE - VIABLE MOLECULES IN THE DILUTE GAS-PHASE

被引:13
作者
EGSGAARD, H
CARLSEN, L
WEISKE, T
SULZLE, D
SCHWARZ, H
机构
[1] NATL ENVIRONM RES INST,DEPT ENVIRONM CHEM,DK-4000 ROSKILDE,DENMARK
[2] RISO NATL LAB,DEPT COMBUST RES,DK-4000 ROSKILDE,DENMARK
[3] TECH UNIV BERLIN,INST ORGAN CHEM,W-1000 BERLIN 12,GERMANY
关键词
D O I
10.1016/0009-2614(92)85025-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nitrosamide, NH2NO, has been generated and characterized in the dilute gas phase by means of neutralization reionization mass spectrometry in combination with extensive isotopic labelling. The molecule was found to be stable under these conditions having a minimal lifetime in the microsecond time frame. No evidence for isomerizations either of the cationic or the neutral nitrosamide was obtained.
引用
收藏
页码:643 / 647
页数:5
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